Publications – CEL Group

Direct Synthesis of High-Valence Protein@UiO-66 Composites: Linking Crystallization Pathways to Protein Encapsulation

J. Cases Díaz, J. Glatz, E. Merced Olivas, R. Pons, J.P. Patterson, M. Giménez-Marqués Advanced Materials, 2026

DOI: 10.1002/adma.202521603

Tailored ZIF-8 morphologies enable efficient chemical recycling of polycarbonate waste

P. Jutrzenka Trzebiatowska, M. Adam Baluk, I. Olazabal, M. Gazda, G. Perli, H. Sardon, M. Giménez-Marqués, A. Zaleska-Medynska Journal of Environmental Chemical Engineering, 2026 14 2 121736

DOI: 10.1016/j.jece.2026.121736

2D MOF with Intrinsic Porosity for Colorimetric Volatile Organic Compounds (VOCs) Detection

S.R. Gamarra, A. Fernández-Alarcón, J. Calbo, E. Ortí, G. Mínguez Espallargas Advanced Materials, 2026 e19243

DOI: 10.1002/adma.202519243

A Cu-Based Near-IR Active MOF with an Ion-Pair Guest Exhibiting Versatile and Selective Gas-Solid Reactivity

R. Saha, A. Cortés-Villena, S. Gómez-Coca, A. Fernández-Alarcón, J. Calbo, R. E. Galian, E. Ortí, E. Ruiz, M. Giménez-Marqués, S. Benmansour, C. J. Gómez-García Advanced Materials, 2025 13485

DOI: 10.1002/adma.202513485

Direct synthesis of an iron metal-organic framework antiferromagnetic glass

L. León-Alcaide, L. Martínez-Goyeneche, M. Sessolo, B. J. C. Vieira, J. C. Waerenborgh, J. A. Rodríguez-Velamazán, O. Fabelo, M. J. Cliffe, D. A. Keen, G. Mínguez Espallargas Nature Communications, 2025 16 8783

DOI: 10.1038/s41467-025-63837-w

Melt-quenched synthesis of a manganese ZIF glass

L. León-Alcaide, A. Fernández-Alarcón, J. Calbo, D.A. Keen,G. Mínguez Espallargas Chemical Communications, 2025 61 11641-11644

DOI: 10.1039/D5CC02342D

Solvent-free approach for the synthesis of heterometallic Fe–Zn-ZIF glass via a melt-quenched process

L. León-Alcaide, C. Castillo-Blas, V. Martin-Diaconescu, I. da Silva, D.A. Keen, T.D. Bennett, G. Mínguez Espallargas Chemical Science, 2025 16 7946-7955

DOI: 10.1039/D5SC00767D

Channel-Directed Enzymatic Depolymerization within a Metal–Organic Framework

J. Glatz, J. Cases Díaz, J. Salinas-Uber, D. Talens-Perales, J. Polaina, M. Giménez-Marqués ACS Applied Materials & Interfaces, 2025

DOI: https://doi.org/10.1021/acsami.5c04137

Implementing magnetic properties on demand with a dynamic lanthanoid–organic framework

I. Gómez-Muñoz, Z. Hu, I. Vitórica-Yrezábal, E. Coronado, G. Mínguez Espallargas Chemical Science, 2025 16 2879-2885

DOI: https://doi.org/10.1039/d4sc07042a

Heteroepitaxial MOF-on-MOF Photocatalyst for Solar-Driven Water Splitting

T. Le Huec, A. López-Francés, I. Abánades Lázaro, S. Navalón, H.G Baldoví, M. Giménez-Marqués ACS Nano, 2024 18 31 20201

DOI: 10.1021/acsnano.4c03442

New porous materials Bidimensional materials

Related projects

MOF-SHELL: use of Metal-Organic Frameworks for functional and protective covering of advanced materials Appore: New routes for the applications of porous materials AVANT: Advanced porous materials

Metal–organic frameworks for biological applications

I. Abánades Lázaro, X. Chen, M. Ding, A. Eskandari, D. Fairen-Jimenez, M. Giménez-Marqués, R. Gref, W. Lin, T. Luo, R.S. Forgan Nature Reviews Methods Primers, 2024 4 42

DOI: 10.1038/s43586-024-00320-8

New porous materials Biohybrid Materials

Related projects

Acquisition of scientific equipment to complete the Laboratory for Magnetostructural Characterization of the ICMol Appore: New routes for the applications of porous materials

Alternative protein encapsulation with MOFs: overcoming the elusive mineralization of HKUST-1 in water

J. Cases Díaz, M. Giménez-Marqués Chem. Commun, 2024 60 51

DOI: 10.1039/D3CC04320G

A zero-valent palladium cluster-organic framework

X. Liu, J.N. McPherson, C.E. Andersen, M.S.B. Jørgensen, R.W. Larsen, N.J. Yutronkie, F. Wilhelm, A. Rogalev, M. Giménez-Marqués, G. Mínguez Espallargas, C.R. Göb, K.S. Pedersen Nat Commun, 2024 15 1177

DOI: 10.1038/s41467-024-45363-3

Symmetrical reconversion: measuring cross-correlation rates with enhanced accuracy

P. Pelupessy, G. Mínguez Espallargas, G. Bodenhausen J. Magn. Res. , 2011-2003 161 258

Involving metals in halogen-halogen interactions: second-sphere Lewis acid ligands for perhalometallate ions (M–X…X’–C)

L. Brammer, G. Mínguez Espallargas, H. Adams CrystEngComm, 2011-2003 5 343

Complementary features of inorganic and organic halogens: application to crystal engineering

L. Brammer, F. Zordan, G. Mínguez Espallargas, S. L. Purver, L. Arroyo Marín, H. Adams, P. Sherwood Trans. Am. Crystallogr. Assoc. , 2011-2003 39 114

Designing intermolecular interactions between halogenated peripheries of inorganic and organic molecules: electrostatically directed M–X…X’–C halogen bonds

G. Mínguez Espallargas, L. Brammer, P. Sherwood Angew. Chem. Int. Ed. , 2011-2003 45 435

Unexpected structural homologies involving hydrogen-bonded and halogen bonded networks in halopyridinium halometallate salts

F. Zordan, G. Mínguez Espallargas, L. Brammer CrystEngComm, 2011-2003 8 425

Reversible extrusion and uptake of HCl molecules by crystalline solids involving coordination bond cleavage and formation

G. Mínguez Espallargas, L. Brammer, J. van de Streek, K. Shankland, A. J. Florence, H. Adams J. Am. Chem. Soc. , 2011-2003 128 9584

Ligand flexibility and framework rearrangement in a new family of porous Metal-Organic Frameworks

S. M. Hawxwell, G. Mínguez Espallargas, D. Bradshaw, M. J. Rosseinsky, T. J. Prior, A. J. Florence, J. van de Streek, L. Brammer Chem. Commun. , 2011-2003 1532

Reversible gas uptake by a non-porous crystalline solid involving multiple changes in covalent bonding

G. Mínguez Espallargas, M. Hippler, A. J. Florence, P. Fernandes, J. van de Streek, M. Brunelli, W. I. F. David, K. Shankland, L. Brammer J. Am. Chem. Soc. , 2011-2003 129 15606

Ligand substitution within non-porous crystals of a coordination polymer: elimination from and insertion into Ag−O bonds by alcohol molecules in a solid-vapor reaction

S. Libri, M. Mahler, G. Mínguez Espallargas, D. C. N. G. Singh, J. Soleimannejad, H. Adams, M. D. Burgard, N. P. Rath, M. Brunelli, L. Brammer Angew. Chem. Int. Ed. , 2011-2003 47 1693

Non-covalent interactions under extreme conditions: high pressure and low temperature diffraction studies of the isostructural metal-organic networks (4-chloropyridinium)2[CoX4] (X = Cl, Br)

G. Mínguez Espallargas, L. Brammer, D. R. Allan, C. R. Pulham, N. Robertson, J. E. Warren J. Am. Chem. Soc. , 2011-2003 130 9058

Competition between coordination network and halogen bond network formation: towards halogen-bond functionalised network materials using copper-iodobenzoate units

P. Smart, G. Mínguez Espallargas, L. Brammer CrystEngComm, 2011-2003 10 1335

Combining metals with halogen bonds

L. Brammer, G. Mínguez Espallargas, S. Libri CrystEngComm, 2011-2003 10 1712

Manganese (III) compounds of phenol− pyrazole-based ligands: synthesis, crystal structure, magnetic, and thermal properties

M. Viciano-Chumillas, M. Giménez-Marqués, S. Tanase, M. Evangelisti, I. Mutikainen, U. Turpeinen, J. M. M. Smits, R. de Gelder, L. J. de Jongh, J. Reedijk J. Phys. Chem. C , 2011-2003 112 20525

Rational modification of the hierarchy of intermolecular interactions in molecular crystal structures

G. Mínguez Espallargas, F. Zordan, L. Arroyo Marín, H. Adams, K. Shankland, J. van de Streek, L. Brammer Chem. Eur. J. , 2011-2003 15 7554

Multifunctional magnetic materials obtained by insertion of a spin crossover FeIII complex into bimetallic oxalate-based ferromagnets

M. Clemente-León, E. Coronado, M. López-Jordà, G. Mínguez Espallargas, A. Soriano-Portillo, J. C. Waerenborgh Chem. Eur. J. , 2011-2003 16 2207

Effects of halogen bonding in ferromagnetic chains based on Co(II) coordination polymers

J. M. Clemente-Juan, E. Coronado, G. Mínguez Espallargas, H. Adams, L. Brammer CrystEngComm, 2011-2003 12 2339

Giant Crown‐Shaped Polytungstate Formed by Self‐Assembly of CeIII‐Stabilized Dilacunary Keggin Fragments

S. Reinoso, M. Giménez‐Marqués, J. R. Galán‐Mascarós, P. Vitoria, J. M. Gutiérrez‐Zorrilla Angew. Chem. Int. Ed. , 2011-2003 49 8384

Mechanistic insights into a gas–solid reaction in molecular crystals: the role of hydrogen bonding

G. Mínguez Espallargas, J. van de Streek, P. Fernandes, A. J. Florence, M. Brunelli, K. Shankland, L. Brammer Angew. Chem. Int. Ed. , 2011-2003 49 8892

Different structural destinations: comparing reactions of [CuBr2(3-Brpy)2] crystals with HBr and HCl gas

G. Mínguez Espallargas, A. J. Florence, J. van de Streek, L. Brammer CrystEngComm , 2011-2003 13 4400

Combination of magnetic susceptibility and electron paramagnetic resonance to monitor the 1D to 2D solid state transformation in flexible metal−organic frameworks of Co(II) and Zn(II) with 1,4- bis(triazol-1-ylmethyl)benzene

E. Coronado, M. Giménez-Marqués, G. Mínguez Espallargas Inorg. Chem., 2012 51 4403

One dimensional organization of free radicals via halogen bonding

G. Mínguez Espallargas, A. Recuenco, F. M. Romero, L. Brammer, S. Libri CrystEngComm , 2012 14 6381

Mononuclear and dinuclear manganese compounds stabilized by supramolecular interactions

M. Viciano-Chumillas, M. Giménez-Marqués, S. Tanase, I. Mutikainen, U. Turpeinen, J. M. M. Smits, R. de Gelder, L. J. de Jongh, J. Reedijk Dalton Trans., 2012 41 10249

Tuning the magneto-structural properties in non-porous coordination polymers through HCl chemisorption

E. Coronado, M. Giménez-Marqués, G. Mínguez Espallargas, L. Brammer Nature Commun, 2012 3 828

Dynamic magnetic materials based on the cationic coordination polymer [Cu(btix)2]2n+ (btix = 1,4-bis(triazol-1-ylmethyl)benzene): tuning the structural and magnetic properties through anion exchange

E. Coronado, M. Giménez-Marqués, C. J. Gómez-García, G. Mínguez Espallargas Inorg. Chem. , 2012 51 12938

A novel coordination polymer with an unusual [3×2] oblique copper(II) grid: [Cu2(HBIMAM)2(C4O4)3(H2O)2]n·2nH2O [BIMAM = bis(imidazol-2-yl) methylaminomethane]. X-Ray structure and magnetic characterization

E. Escrivá, L. Soto, J. Server-Carrió, C. J. Gómez-García, G. Mínguez Espallargas, N. Ruiz, A. Sancho, J. García-Lozano, C. Ramírez de Arellano Polyhedron , 2013 56 90

Hybrid magnetic superconductors formed by TaS2 layers and spin crossover complexes

E. Coronado, M. Giménez-Marqués, C. Martí-Gastaldo, G. Mínguez Espallargas, E. Navarro-Moratalla, J. Waerenborgh Inorg. Chem. , 2013 52 8451

Preface: 40th International Conference on Coordination Chemistry

G. Mínguez Espallargas Coord. Chem. Rev. , 2013 257 2419

Hydrogen bonding versus π-stacking in ferromagnetic interactions. Studies on a copper triazolopyridine complex

C. Ramírez de Arellano, E. Escrivà, C. J. Gómez-García, G. Mínguez Espallargas, R. Ballesteros, B. Abarca CrystEngComm , 2013 15 1836

Chemical transformations of a crystalline coordination polymer: a multi-stage solid-vapor reaction manifold

I. J. Vitorica-Yrezabal, G. Mínguez Espallargas, J. Soleimannejad, A. J. Florence, A. J. Fletcher, L. Brammer Chem. Sci. , 2013 4 696

Dynamic magnetic MOFs

E. Coronado, G. Mínguez Espallargas Chem. Soc. Rev. , 2013 42 1525

A family of layered chiral porous magnets exhibiting tunable ordering temperatures

M. Atzori, S. Benmansour, G. Mínguez Espallargas, M. Clemente-León, A. Abhervé, P. Gómez-Claramunt, E. Coronado, F. Artizzu, E. Sessini, P. Deplano, A. Serpe, M. L. Mercuri, C. J. Gómez García Inorg. Chem. , 2013 52 10031

Single-crystal EPR spectroscopy of Co(II) Single-Chain Magnets

A. Amjad, G. Mínguez Espallargas, J. Liu, J. M. Clemente-Juan, E. Coronado, S. Hill, E. del Barco Polyhedron, 2013 66 218

Spin-crossover modification through selective CO2 sorption

E. Coronado, M. Giménez-Marqués, G. Mínguez Espallargas, F. Rey, I. J. Vitórica-Yrezábal J. Am. Chem. Soc. , 2013 135 15986

Structural re-arrangement in two hexanuclear CuII complexes: from a spin frustrated trigonal prism to a strongly coupled antiferromagnetic soluble ring complex with a porous tubular structure

W. Cañon-Mancisidor, C. J. Gómez-García, G. Mínguez Espallargas, A. Vega, E. Spodine, D. Venegas- Yazigi, E. Coronado Chem. Sci. , 2014 5 324

Perovskite solar cells employing organic charge-transport layers

O. Malinkiewicz, A. Yella, Y. H. Lee, G. Mínguez Espallargas, M. Graetzel, M. K. Nazeeruddin, H. J. Bolink Nature Photon. , 2014 8 128

Non-template synthesis of CH3NH3PbBr3 perovskite nanoparticles

L. C. Schmidt, A. Pertegás, S. González-Carrero, O. Malinkiewicz, S. Agouram, G. Mínguez Espallargas, H. J. Bolink, R. E. Galian, J. Pérez-Prieto J. Am. Chem. Soc. , 2014 136 850

Flexible high efficiency perovskite solar cells

C. Roldán-Carmona, O. Malinkiewicz, A. Soriano, G. Mínguez Espallargas, A. Garcia, P. Reinecke, T. Kroyer, M. I. Dar, M. K. Nazeeruddin, H. J. Bolink Energy Environ. Sci. , 2014 7 994

A mixed-ligand approach for spin-crossover modulation in a linear FeII coordination polymer

N. Calvo Galve, E. Coronado, M. Giménez-Marqués, G. Mínguez Espallargas Inorg. Chem. , 2014 53 4482

A SIM-MOF: three-dimensional organisation of Single-Ion Magnets with anion-exchange capabilities

J. J. Baldoví, E. Coronado, A. Gaita-Ariño, C. Gamer, M. Giménez-Marqués, G. Mínguez Espallargas Chem. Eur. J. , 2014 20 10695

A rare example of nickel(II) chains based on a heteroscorpionate-like ligand with quadruple imidazolyl interactions

C. J. Gómez-García, E. Escrivà, G. Mínguez Espallargas, J. J. Borrás-Almenar, L. Soto, A. Sancho, J. García-Lozano, C. Ramírez de Arellano Dalton Trans. , 2014 43 11371

Blue-luminescent organic lead bromide perovskites: highly dispersible and photostable materials

S Gonzalez-Carrero, G Mínguez Espallargas, RE Galian, J Pérez-Prieto J. Mater. Chem. A, 2015 3 14039

DOI: 10.1039/C5TA01765C

Layered gadolinium hydroxides for low-temperature magnetic cooling

Gonzalo Abellán, Guillermo Mínguez Espallargas, Giulia Lorusso, Marco Evangelisti, Eugenio Coronado Chem. Commun., 2015 51 14207

DOI: 10.1039/C5CC05150A

Quantum Error Correction with magnetic molecules

JJ Baldoví, S Cardona-Serra, JM Clemente-Juan, L Escalera-Moreno, A Gaita-Ariño, G Mínguez Espallargas Europhysics Letters, 2015 110 3

DOI: 10.1209/0295-5075/110/33001

2D and 3D Anilato-Based Heterometallic M(I)M(III) Lattices: The Missing Link

S Benmansour, C Valles-Garcia, P Gomez-Claramunt, G Minguez Espallargas, CJ Gomez-Garcia Inorg. Chem. , 2015 54 11 5410

DOI: 10.1021/acs.inorgchem.5b00451

Unravelling the chemical design of spin-crossover nanoparticles based on iron(II)–triazole coordination polymers: towards a control of the spin transition

M Giménez-Marqués, ML Garcia-Sanz de Larrea, E Coronado J. Mater. Chem. C, 2015 3 7946

DOI: 10.1039/C5TC01093D

Coordination Polymer Flexibility Leads to Polymorphism and Enables a Crystalline Solid–Vapour Reaction: A Multi-technique Mechanistic Study

IJ Vitórica‐Yrezábal, S Libri, JR Loader, G Minguez Espallargas, M Hippler, AJ Fletcher, SP Thompson, JE Warren, D Musumeci, MD Ward, L Brammer Chem. Eur. J., 2015 21 8799

DOI: 10.1002/chem.201500514

Spin Switching in Electronic Devices Based on 2D Assemblies of Spin-Crossover Nanoparticles

J Dugay, M Giménez‐Marqués, T Kozlova, HW Zandbergen, E Coronado, HSJ van der Zant Adv.Mater., 2015 27 1288

DOI: 10.1002/adma.201404441

Solvent-Free Synthesis of a Pillared Three-Dimensional Coordination Polymer with Magnetic Ordering

J Lopez-Cabrelles, M Gimenez-Marques, G Minguez Espallargas, E Coronado Inorg. Chem. , 2015 54 21 10490

DOI: 10.1021/acs.inorgchem.5b02003

Snapshots of a solid-state transformation: coexistence of three phases trapped in one crystal

G Aromí, CM Beavers, J Sánchez Costa, GA Craig, G Mínguez Espallargas, A Orera, O Roubeau Chem. Sci, 2016 7 2907

DOI: 10.1039/C5SC04287A

Isostructural compartmentalized spin-crossover coordination polymers for gas confinement

N Calvo Galve, M Giménez-Marqués, M Palomino, S Valencia, F Rey, G Mínguez Espallargas, E Coronado Inorg. Chem. Front, 2016 3 808

DOI: 10.1039/C5QI00277J

Key Role of the Cation in the Crystallization of Chiral Tris(Anilato)Metalate Magnetic Anions

S Benmansour, P Gomez-Claramunt, C Valles-Garcia, G Minguez Espallargas, CJ Gomez Garcia Cryst. Growth Des. , 2016 16 1 518

DOI: 10.1021/acs.cgd.5b01573

Influence of functionalization of terephthalate linker on the catalytic activity of UiO-66 for epoxide ring opening

Juan F Blandez, Andrea Santiago-Portillo, Sergio Navalón, Mónica Giménez-Marqués, Mercedes Álvaro, Patricia Horcajada, Hermenegildo García Journal of Molecular Catalysis A: Chemical, 2016 425 332

DOI: 10.1016/j.molcata.2016.10.022

Insertion of a [FeII(pyimH)3]2+ [pyimH = 2-(1H-Imidazol-2-yl)pyridine] Spin-Crossover Complex Inside a Ferromagnetic Lattice Based on a Chiral 3D Bimetallic Ox¬alate Network

M López‐Jordà, M Giménez‐Marqués, C Desplanches, G Minguez Espallargas, M Clemente‐León, E Coronado Eur. J. Inorg. Chem, 2016 2187

DOI: 10.1002/ejic.201500790

Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]

J López-Cabrelles, G Mínguez Espallargas, E Coronado Polymers, 2016 8 171

DOI: 10.3390/polym8050171

Nanostructured metal–organic frameworks and their bio-related applications

M Giménez-Marqués, T Hidalgo, C Serre, P Horcajada Coordination Chemistry Reviews, 2016 307 2 342

DOI: https://doi.org/10.1016/j.ccr.2015.08.008

Tunable crossover between one- and three-dimensional magnetic dynamics in CoII single-chain magnets organized by halogen bonding

A Amjad, JM Clemente-Juan, E Coronado, F Luis, M Evangelisti, G Mínguez Espallargas, E del Barco Phys. Rev. B, 2016 93 224418

DOI: 10.1103/PhysRevB.93.224418

Insertion of a [FeII(pyimH)3]2+ [pyimH = 2-(1H-Imidazol-2-yl)pyridine] Spin-Crossover Complex Inside a Ferromagnetic Lattice Based on a Chiral 3D Bimetallic Oxalate Network

M López‐Jordà, M Giménez‐Marqués, C Desplanches, G Minguez Espallargas, M Clemente‐León, E Coronado Eur. J. Inorg. Chem, 2016 2187

DOI: 10.1002/ejic.201500790

New dinuclear copper complexes incorporating bis(imidazolyl) based ligands and bidentate–monodentate oxalate bridges. Crystal structure and magnetic properties of [Cu2(BIM)2(C2O4)2]·4H2O and [Cu2(BIK)2(C2O4)2] (BIM = bis(2-imidazolyl)methane), BIK = bis(2-imidazolyl)ketone). Exploring magneto-structural correlations

E Escriva, JV Folgado, G Mínguez Espallargas, L Soto, A Sancho, L Perello, R Ortiz Polyhedron, 2016 112 137

DOI: 10.1016/j.poly.2016.03.041

Near Room-Temperature Memory Devices Based on Hybrid Spin-Crossover@SiO 2 Nanoparticles Coupled to Single-Layer Graphene Nanoelectrodes

A Holovchenko, J Dugay, M Giménez‐Marqués, R Torres‐Cavanillas, E Coronado, HSJ van der Zant Adv.Mater., 2016 28 7228

DOI: 10.1002/adma.201600890

Adaptability of the metal(III,IV) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically active MOFs

G Mouchaham, B Abeykoon, M Giménez-Marqués, S Navalon, A Santiago-Portillo, M Affram, N Guillou, C Martineau, H Garcia, A Fateeva, T Devic Chem. Commun, 2017 53 7661

DOI: 10.1039/C7CC04215A

Phase Transitions in Spin-Crossover Thin Films Probed by Graphene Transport Measurements

J Dugay, M Aarts, M Giménez-Marqués, T Kozlova, HW Zandbergen, E Coronado, HSJ Van Der Zant Nano Lett. , 2017 17 1 186

DOI: 10.1021/acs.nanolett.6b03780

Guillevic, R Simón-Vázquez, A González-Fernández, C Serre, MJ Alonso, P Horcajada Chitosan-coated mesoporous MIL-100(Fe) nanoparticles as improved bio-compatible oral nanocarriers

T Hidalgo, M Giménez-Marqués, E Bellido, J Avila, MC Asensio, F Salles, MV Lozano, M Scientific Reports, 2017 7 43099

DOI: 10.1038/srep43099

A Smart Metal–Organic Framework Nanomaterial for Lung Targeting

T Simon‐Yarza, M Giménez‐Marqués, R Mrimi, A Mielcarek, R Gref, P Horcajada, C Serre, P Couvreur Angew.Chem. , 2017 129 15771

DOI: 10.1002/ange.201707346

Gas confinement in compartmentalized coordination polymers for highly selective sorption

M Giménez-Marqués, NC Galve, M Palomino, S Valencia, F Rey, G Sastre, IJ Vitórica-Yrezábal, M Jiménez-Ruiz, JA Rodríguez-Velamazán, MA González, JL Jordá, E Coronado, G Mínguez Espallargas Chem. Sci., 2017 8 3109

DOI: 10.1039/C6SC05122G

Sublimable chloroquinolinate lanthanoid single-ion magnets deposited on ferromagnetic electrodes

SG Miralles, A Bedoya-Pinto, JJ Baldoví, W Canon-Mancisidor, Y Prado, H Prima-Garcia, A Gaita-Arino, G Mínguez Espallargas, LE Hueso, E Coronado Chem. Sci., 2018 9 199

DOI: 10.1039/C7SC03463F

A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst

M Souto, A Santiago-Portillo, M Palomino, IJ Vitórica-Yrezábal, BJC Vieira, JC Waerenborgh, S Valencia, S Navalón, F Rey, H García, G Mínguez Espallargas Chem. Sci., 2018 9 2413

DOI: 10.1039/C7SC04829G

Two consecutive magneto-structural gas-solid transformations in non-porous molecular materials

J Miguel-Donet, J López Cabrelles, N Calvo Galve, E Coronado Miralles, G Mínguez Espallargas Chemistry-A European Journal, 2018 24 47 12426

DOI: 10.1002/chem.201802510

Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal–Organic Framework

M Souto, J Romero, J Calbo, IJ Vitórica-Yrezábal, JL Zafra, J Casado, E Ortí, A Walsh, G Mínguez Espallargas J. Am. Chem. Soc. , 2018 140 33 10562

DOI: 10.1021/jacs.8b05890

Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization

J López-Cabrelles, S Mañas-Valero, IJ Vitórica-Yrezábal, PJ Bereciartua, JA Rodríguez-Velamazán, JC Waerenborgh, B JC Vieira, D Davidovikj, PG Steeneken, HSJ Van der Zant, G Mínguez Espallargas, E Coronado Nature chemistry, 2018 10 1001

DOI: 10.1038/s41557-018-0113-9

Charge Mobility and Dynamics in Spin-Crossover Nanoparticles Studied by Time-Resolved Microwave Conductivity

J Dugay, W Evers, R Torres-Cavanillas, M Giménez-Marqués, E Coronado, HSJ Van der Zant J. Phys. Chem. Lett. , 2018 9 19 5672

DOI: 10.1021/acs.jpclett.8b02267

Implementation of slow magnetic relaxation in a SIM-MOF through a structural rearrangement

J Castells-Gil, JJ Baldoví, C Martí-Gastaldo, G Mínguez Espallargas Dalton Transactions , 2018 47 41 14734

DOI: 10.1039/C8DT03421D

Sublimable single ion magnets based on lanthanoid quinolinate complexes: The role of intermolecular interactions on their thermal stability

W Cañon-Mancisidor, SG Miralles, JJ Baldoví, G Mínguez Espallargas, A Gaita-Ariño, E Coronado Inorg. Chem. , 2018 57 22 14170

DOI: 10.1021/acs.inorgchem.8b02080

Metal-Organic Framework Surface Functionalization: GraftFast Surface Engineering to Improve MOF Nanoparticles Furtiveness

M Giménez‐Marqués, E Bellido, T Berthelot, T Simón‐Yarza, T Hidalgo, R Simón‐Vázquez, Á González‐Fernández, J Avila, M Carmen Asensio, R Gref, P Couvreur, C Serre, P Horcajada Small, 2018 14

DOI: 10.1002/smll.201870182

GraftFast Surface Engineering to Improve MOF Nanoparticles Furtiveness

M Giménez‐Marqués, E Bellido, T Berthelot, T Simón‐Yarza, T Hidalgo, R Simón‐Vázquez, Á González‐Fernández, J Avila, M Carmen Asensio, R Gref, P Couvreur, C Serre, P Horcajada Small, 2018 14 1801900

DOI: 10.1002/smll.201801900

Magnetic functionalities in MOFs: from the framework to the pore

G Mínguez Espallargas, E Coronado Chem. Soc. Rev, 2018 47 533

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Design of cost-efficient and photocatalytically active Zn-based MOFs decorated with Cu 2 O nanoparticles for CO 2 methanation

M. Cabrero-Antonino, S. Remiro-Buenamañana, M. Souto, A. A. García-Valdivia, D. Choquesillo-Lazarte, S Navalón, A Rodríguez-Diéguez, G Mínguez Espallargas, H García Chem. Commun, 2019 55 10932

DOI: 10.1039/C9CC04446A

Sensing of the Molecular Spin in Spin-Crossover Nanoparticles with Micromechanical Resonators

J. Dugay, M. Giménez-Marqués, W.J. Venstra, R. Torres-Cavanillas, U.N. Sheombarsing, N, Manca, E. Coronado, H.S.J. Van Der Zant J. Phys. Chem. C , 2019 123 11 6778

DOI: 10.1021/acs.jpcc.8b10096

Covalent and Selective Grafting of Polyethylene Glycol Brushes at the Surface of ZIF-8 for the Processing of Membranes for Pervaporation

M. Benzaqui, R. Semino, F. Carn, S. Rodrigues T.avares, N. Menguy, M. Giménez-Marqués, E. Bellido, P. Horcajada, T. Berthelot, A.I. Kuzminova, M.E. Dmitrenko, A.V. Penkova, D. Roizard, C. Serre, G. Maurin, N. Steunou ACS Sustainable Chem. Eng. , 2019 7 7 6629

DOI: 10.1021/acssuschemeng.8b05587

Cellular Uptake, Intracellular Trafficking, and Stability of Biocompatible Metal-Organic Framework (MOF) Particles in Kupffer Cells

M. Durymanov, A. Permyakova, S. Sene, A. Guo, C. Kroll, M. Giménez-Marqués, C. Serre, J. Reineke Mol. Pharmaceutics , 2019 16 2315

DOI: 10.1021/acs.molpharmaceut.8b01185

Downsizing of robust Fe-triazole@SiO2 spin-crossover nanoparticles with ultrathin shells

R. Torres-Cavanillas, L. Lima-Moya, F.D. Tichelaar, H.W. Zandbergen, M. Giménez Marqués, E. Coronado Dalton Trans., 2019 48 15465

DOI: 10.1039/C9DT02086A

Design of Bistable Gold@Spin-Crossover Core–Shell Nanoparticles Showing Large Electrical Responses for the Spin Switching

R. Torres-Cavanillas, R. Sanchis-Gual, J. Dugay, M. Coronado-Puchau, M. Giménez-Marqués, E. Coronado Adv. Mater, 2019 31 1900039

DOI: 10.1002/adma.201900039

Core–Shell Nanoparticles: Design of Bistable Gold@Spin-Crossover Core–Shell Nanoparticles Showing Large Electrical Responses for the Spin Switching

R Torres-Cavanillas,R Sanchis-Gual, J Dugay, M Coronado-Puchau, M Giménez-Marqués, E Coronado Adv. Mater, 2019 31 27

DOI: 10.1002/adma.201970193

Solvent-free synthesis of ZIFs: a route toward the elusive Fe (II) analogue of ZIF-8

J. López-Cabrelles, J. Romero, G. Abellán, M. Giménez-Marqués, M. Palomino, S. Valencia, F. Rey, G. Mínguez Espallargas J. Am. Chem. Soc. , 2019 141 7173

DOI: 10.1021/jacs.9b02686

Cation influence in adsorptive propane/propylene separation in ZIF-8 (SOD) topology

E. Andres-Garcia, J. López-Cabrelles, L. Oar-Arteta, B. Roldan-Martinez, M. Cano-Padilla, J. Gascon, G. Mínguez Espallargas, F Kapteijn Chemical Engineering Journal, 2019 371 848

DOI: 10.1016/j.cej.2019.04.094

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework

M. Souto, J. Calbo, S. Mañas-Valero, A. Walsh, G. Mínguez Espallargas Beilstein J. Nanotechnol. , 2019 10 1883

DOI: 10.3762/bjnano.10.183

Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks

J. Castells-Gil, S. Mañas-Valero, I.J. Vitórica-Yrezábal, D. Ananias, J. Rocha, R. Santiago, S. T Bromley, J. Baldovi, E. Coronado, M. Souto, G. Minguez Espallargas Chem.Eur.J., 2019 25 12636

DOI: 10.1002/chem.201902855

Downsizing of robust Fe-triazole@SiO2 spin-crossover nanoparticles with ultrathin shells

R. Torres-Cavanillas, L. Lima-Moya, F.D. Tichelaar, H.W. Zandbergen, M. Giménez-Marqués, E. Coronado Dalton Trans., 2019 48 15465

DOI: 10.1039/C9DT02086A

Cobalt Metal–Organic Framework Based on Two Dinuclear Secondary Building Units for Electrocatalytic Oxygen Evolution

S. Gutierrez-Tarrino, J.L. Olloqui-Sariego, J.J. Calvente, M. Palomino, G. Mínguez Espallargas, J.L. Jorda, F. Rey, P. Oña-Burgos ACS Appl. Mater. Interfaces , 2019 11 50 46658

DOI: 10.1021/acsami.9b13655

Use of alkylarsonium directing agents for the synthesis and study of zeolites

S. Saez-Ferre, C.W. Lopes, J. Simancas-Coloma, J.A. Vidal Moya, T. Blasco Lanzuela, G. Agostini, G. Minguez Espallargas, J.L. Jorda Moret, F. Rey Garcia, P. Oña-Burgos Chem.Eur.J., 2019 25 16390

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Hybrid organic–inorganic mononuclear lanthanoid single ion magnets

W. Cañón-Mancisidor, M. Zapata-Lizama, P. Hermosilla-Ibáñez, C. Cruz, D. Venegas-Yazigi, G. Mínguez Espallargas Chem. Commun, 2019 55 14992

DOI: 10.1039/C9CC07868A

Exploring the catalytic performance of a series of bimetallic MIL-100(Fe, Ni) MOFs

M. Giménez-Marqués, A. Santiago-Portillo, S. Navalón, M. Álvaro, V. Briois, F. Nouar, H. Garcia, C. Serre J. Mater. Chem. A, 2019 7 20285

DOI: 10.1039/C9TA01948K

Interpenetrated Luminescent Metal–Organic Frameworks based on 1H-Indazole-5-carboxylic Acid

A.A. Garcı́a-Valdivia, M. Pérez-Mendoza, D. Choquesillo-Lazarte, J. Cepeda, B. Fernández, M. Souto, M. González-Tejero, J.A. Garcı́a, G. Mı́nguez Espallargas, A. Rodrı́guez-Diéguez Cryst. Growth Des. , 2020 20 7 4550

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2D magnetic MOFs with micron-lateral size by liquid exfoliation

L. León-Alcaide, J. López-Cabrelles, G. Mínguez Espallargas, E. Coronado Chem. Commun, 2020 56 7657

DOI: 10.1039/D0CC02982C

Design of stable mixed-metal MIL-101 (Cr/Fe) materials with enhanced catalytic activity for the Prins reaction

C. Vallés-García, E. Gkaniatsou, A. Santiago-Portillo, M. Giménez-Marqués, M. Álvaro, J.M. Greneche, N. Steunou, C. Sicard, S. Navalón, C. Serre, H. García J. Mater. Chem. A, 2020 8 17002

DOI: 10.1039/D0TA02991B

A systematic study of the optical properties of mononuclear hybrid organo–inorganic lanthanoid complexes

M. Zapata-Lizama, P. Hermosilla-Ibáñez, D. Venegas-Yazigi, G. Mínguez Espallargas, L.J. Queiroz Maia, G. Gasparotto, R. Costa De Santana, W. Cañón-Mancisidor Inorg. Chem. Front., 2020 7 3049

DOI: 10.1039/D0QI00232A

MOF-Mediated Synthesis of Supported Fe-doped Pd Nanoparticles under Mild Conditions for Magnetically Recoverable Catalysis

M.D. Darawsheh, J. Mazarío, C.W. Lopes, M. Giménez-Marqués, M.E. Domine, D.M. Meira, J. Martínez, G. Mínguez Espallargas, P. Oña-Burgos Chem. Eur.J. , 2020 26 13659

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Cobalt Metal–Organic Framework Based on Layered Double Nanosheets for Enhanced Electrocatalytic Water Oxidation in Neutral Media

S. Gutiérrez-Tarriño, J.L. Olloqui-Sariego, J.J. Calvente, G. Mínguez Espallargas, F. Rey, A. Corma, P. Oña-Burgos J. Am. Chem. Soc. , 2020 142 45 19198

DOI: 10.1021/jacs.0c08882

Plasmon-assisted spin transition in gold nanostar@spin crossover heterostructures

R. Sanchis-Gual, R. Torres-Cavanillas, M.C. Puchau, M. Giménez-Marqués, E. Coronado J. Mater. Chem. C, 2021 9 10811

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Selective CO2 Sorption Using Compartmentalized Coordination Polymers with Discrete Voids

E. Miguel‐Casañ, E. Andres‐Garcia, J. Calbo, M. Giménez‐Marqués, G. Mínguez Espallargas Chem.Eur.J., 2021 27 4653

DOI: 10.1002/chem.202004845

Near Isotropic D4d Spin Qubits as Nodes of a Gd(III)-Based Metal–Organic Framework

J. López-Cabrelles, L. Escalera-Moreno, Z. Hu, H. Prima-García, G. Mínguez Espallargas, A. Gaita-Ariño, E. Coronado Inorg. Chem. , 2021 60 12 8575

DOI: 10.1021/acs.inorgchem.1c00504

A tris-oxovanadium pyrogallate complex: synthesis, structure, and magnetic and electronic properties

H. Mkhadder, M. Denis, M. Giménez-Marqués, W. Cañón-Mancisidor, B. Humbert, E. Deunf, P. Poizot, T. Devic Dalton Trans., 2021 50 13399

DOI: 10.1039/D1DT01990B

Exploiting reaction‐diffusion conditions to trigger pathway complexity in the growth of a MOF

J. Puigmartí-Luis, N.C. Galve, A. Abrishamkar, A. Sorrenti, L. Di Rienzo, M Satta, M. D'Abramo, E. Coronado, A.J. deMello, G. Mínguez Espallargas Angew.Chem.Int.Ed., 2021 60 15920

DOI: 10.1002/anie.202101611

Functionalization using biocompatible carboxylated cyclodextrins of iron-based nanoMIL-100

T. Carmona, J.F. Marco, M. Giménez-Marqués, W. Cañón-Mancisidor, M. Gutiérrez-Cutiño, P. Hermosilla-Ibáñez, E. G. Pérez, G. Mínguez Espallargas, D. Venegas-Yazigi Polyhedron, 2021 210 115509

DOI: 10.1016/j.poly.2021.115509

Slow Relaxation of the Magnetization on Frustrated Triangular FeIII Units with S = 1/2 Ground State: The Effect of the Highly Ordered Crystal Lattice and the Counteranions

W. Cañón-Mancisidor, P. Hermosilla-Ibáñez, E. Spodine, V. Paredes-García, C.J. Gómez-García, G. Mínguez Espallargas, D. Venegas-Yazigi Cryst. Growth Des. , 2021 21 11 6213

DOI: 10.1021/acs.cgd.1c00640

Fast Polymeric Functionalization Approach for the Covalent Coating of MoS2 Layers

I. Gómez-Muñoz, S. Laghouati, R. Torres-Cavanillas, M. Morant-Giner, N.V. Vassilyeva, A. Forment-Aliaga, and M. Giménez-Marqués ACS Appl. Mater. Interfaces , 2021 13 30 36475

DOI: 10.1021/acsami.1c08294

Chemical design and magnetic ordering in thin layers of 2D MOFs

J. López-Cabrelles, S. Mañas-Valero, I.J. Vitórica-Yrezábal, M. Šiškins, M. Lee, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado J. Am. Chem. Soc. , 2021 143 44 18502

DOI: 10.1021/jacs.1c07802

Spin-crossover nanoparticles anchored on MoS2 layers for heterostructures with tunable strain driven by thermal or light-induced spin switching

R. Torres-Cavanillas, M. Morant-Giner, G. Escorcia-Ariza, J. Dugay, J. Canet-Ferrer, S. Tatay, S. Cardona-Serra, M. Giménez-Marqués, M. Galbiati, A. Forment-Aliaga, E. Coronado Nat. Chem. , 2021 13 1101

DOI: 10.1038/s41557-021-00795-y

A thermally/chemically robust and easily regenerable anilato-based ultramicroporous 3D MOF for CO2 uptake and separation

N.N. Monni, E. Andrés-García, K. Caamaño, V. García-López, J.M.C. Juan, M. Giménez-Marqués, M.M. Oggianu, G. Mínguez Espallargas, M. Clemente Leon, M.L. Mercuri, E. Coronado J. Mater. Chem. A, 2021 9 25189

DOI: 10.1039/D1TA07436A

Boosting Protein Encapsulation through Lewis-Acid-Mediated Metal–Organic Framework Mineralization: Toward Effective Intracellular Delivery”

J. Cases Díaz, B. Lozano-Torres, M. Giménez-Marqués Chem. Mater., 2021 34 17 7817

DOI: 10.1021/acs.chemmater.2c01338

Biohybrid Materials Bidimensional materials New porous materials

Spin-crossover nanoparticles anchored on MoS2 layers for heterostructures with tunable strain driven by thermal or light-induced spin switching

R. Torres-Cavanillas, M. Morant-Giner, G. Escorcia-Ariza, J. Dugay, J. Canet-Ferrer, S. Tatay, S. Cardona-Serra, M. Giménez-Marqués, M. Galbiati, A. Forment-Aliaga, E. Coronado Nat. Chem. , 2021 1311011109

DOI: 10.1038/s41557-021-00795-y

Bidimensional materials

Multivariate sodalite Zeolitic Imidazolate frameworks: a direct solvent-free synthesis

J. López-Cabrelles, E. Miguel-Casañ, M. Esteve-Rochina, E. Andres-Garcia, I. Vitórica-Yrezábal, J. Calbo, G Minguez Espallargas Chem. Sci., 2022 13 842

DOI: 10.1039/D1SC04779E

A fluorinated 2D magnetic coordination polymer

J. López-Cabrelles, S. Mañas-Valero, I.J. Vitórica-Yrezábal, P.J. Bereciartua, E. Coronado, G. Minguez Espallargas Dalton Trans., 2022 51 1861

DOI: 10.1039/D1DT03734J

Exploiting redox activity of MIL-100(Fe) carrier enables carvacrol prolonged antimicrobial activity

K. Caamaño, J. Calbo, R. Heras-Mozos, J.C. Waerenborgh, B.J.C. Vieira, P.M. Hernández-Muñoz, R. Gavara, M. Giménez-Marqués ACS Appl. Mater. Interfaces , 2022 14 8 10758

DOI: 10.1021/acsami.1c21555

Synthesis, Structures, and Solution Studies of a New Class of [Mo2O2S2]-Based Thiosemicarbazone Coordination Complexes

A. Fuior, D. Cebotari, M. Haouas, J. Marrot, G. Minguez Espallargas, V. Guérineau, D. Touboul, R.V. Rusnac, A. Gulea, S. Floquet ACS Omega , 2022 7 19 16547

DOI: 10.1021/acsomega.2c00705

Semiconductor Porous Hydrogen-Bonded Organic Frameworks Based on Tetrathiafulvalene Derivatives

M. Vicent-Morales, M. Esteve-Rochina, J. Calbo, E. Ortí, I.J. Vitórica-Yrezábal, G. Mínguez Espallargas J. Am. Chem. Soc. , 2022 144 20 9074

DOI: 10.1021/jacs.2c01957

Boosting Protein Encapsulation through Lewis-Acid-Mediated Metal–Organic Framework Mineralization: Toward Effective Intracellular Delivery

J. Cases Díaz, B. Lozano-Torres, M. Giménez-Marqués Chem. Mater. , 2022 34 17 7817

DOI: 10.1021/acs.chemmater.2c01338

Boosting Protein Encapsulation through Lewis-Acid-Mediated Metal–Organic Framework Mineralization: Toward Effective Intracellular Delivery”

J. Cases Díaz, B. Lozano-Torres, M. Giménez-Marqués Chem. Mater., 2022 34 17 7817

DOI: 10.1021/acs.chemmater.2c01338

Biohybrid Materials Bidimensional materials New porous materials

Adsorptive Separation of CO2 by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions

L. Gan, E. Andres-Garcia, G. Mínguez Espallargas, J. Giner Planas ACS Appl. Mater. Interfaces , 2023 15 4 5309

DOI: 10.1021/acsami.2c20373

Ultramicroporous iron-isonicotinate MOFs combining size-exclusion kinetics and thermodynamics for efficient CO2/N2 gas separation

I. Abánades Lázaro, E. C. Mazarakioti, E. Andres-Garcia, B. J. C. Vieira, J. C. Waerenborgh, I. J. Vitórica-Yrezábal, M. Giménez-Marqués, G. Mínguez Espallargas J. Mater. Chem. A, 2023 11 5320

DOI: 10.1039/D2TA08934C

Meltable, Glass-Forming, Iron Zeolitic Imidazolate Frameworks

L. León-Alcaide, R.S. Christensen, D.A. Keen, J.L. Jordá, I. Brotons-Alcázar, A. Forment-Aliaga, G. Mínguez Espallargas J. Am. Chem. Soc. , 2023 145 20 11258

DOI: 10.1021/jacs.3c01455

Vapor-phase synthesis of low-valent metal–organic frameworks from metal carbonyl synthons

C. E. Andersen, J. N. McPherson, M. Giménez-Marqués, J. Li, M. Kubus, S. Ito, C. R. Göb, S. Ott, R. W. Larsen, G. Mínguez Espallargas, K. S. Pedersen J. Mater. Chem. C, 2023 11 11460

DOI: 10.1039/D3TC02088F

Imparting structural robustness of metal–organic cages based on oxo-dimolybdenum clusters

S. Delaporte, I. Abánades Lázaro, J. López-Cabrelles, E. C. Mazarakioti, S. Chebourou, I. J. Vitórica-Yrezábal, M. Giménez-Marqués, G. Mínguez Espallargas Dalton Trans., 2023 52 15682

DOI: 10.1039/D3DT02482B

Hierarchical mesoporous NanoMUV-2 for the selective delivery of macromolecular drugs

I. Abánades Lázaro, M. Vicent-Morales, G. Mínguez Espallargas, M. Giménez-Marqués J. Mater. Chem. B, 2023 11 9179

DOI: 10.1039/D3TB01819A

ZIF-8 encapsulation improves the antifungal activity of benzaldehyde and methyl anthranilate in films

K. Caamaño, G. López-Carballo, R. Heras-Mozos, J. Glatz, P. Hernández-Muñoz, R. Gavara, M. Giménez-Marqués Dalton Trans., 2023 52 17993

DOI: 10.1039/D3DT03229A

Implementing Mesoporosity in Zeolitic Imidazolate Frameworks through Clip-Off Chemistry in Heterometallic Iron–Zinc ZIF-8

L. León-Alcaide, J. López-Cabrelles, M. Esteve-Rochina, E. Ortí, J. Calbo, B.A.H. Huisman, M. Sessolo, J.C. Waerenborgh, B.J.C. Vieira, G. Mínguez Espallargas J. Am. Chem. Soc. , 2023 145 42 23249

DOI: 10.1021/jacs.3c08017