<p>In this research line we undertake the synthesis of different types of crystalline porous materials, including extended porous metal-organic frameworks (MOFs), and more advanced solution-processable porous materials such as hydrogen-bonded organic frameworks (HOFs) and metal-organic polyhedra (MOPs). We cover from their synthesis with control over the crystalline size to their advanced physico-chemical characterization and further implementation. We investigate the potential of these novel porous materials for gas separations and carbon dioxide capture, as well as for sensing and for light-harvesting and photocatalysis.</p>